Entropy Production in Oscillating Chemical Systems

Tutorial Review: Simulation of Oscillating Chemical Reactions Using Microsoft Excel Macros

Oscillating reactions are one of the most interesting topics in chemistry and analytical chemistry. Fluctuations in concentrations of one the reacting species (usually a reaction intermediate) create an oscillating chemical reaction. In oscillating systems, the reaction is far from thermodynamic equilibrium. In these systems, at least one autocatalytic step is required. Developing an instinctiv...

Comparison of entropy generation minimization principle and entransy theory in optimal design of thermal systems

In this study, the relationship among the concepts of entropy generation rate, entransy theory, and generalized thermal resistance to the optimal design of thermal systems is discussed. The equations of entropy and entransy rates are compared and their implications for optimization of conductive heat transfer are analyzed. The theoretical analyses show that based on entropy generation minimizat...

Phase Tuning in Synchronization of Nonlinear Master-slave Oscillating Systems Using Decomposition Method

Algorithms for Computing Limit distributions of Oscillating Systems with Finite Capacity

We address the batch arrival  systems with finite capacity under partial batch acceptance strategy where service times or rates oscillate between two forms according to the evolution of the number of customers in the system. Applying the theory of Markov regenerative processes and resorting to Markov chain embedding, we present a new algorithm for computing limit distributions of the number cus...

Linear nonequilibrium thermodynamics of reversible periodic processes and chemical oscillations.

Onsager's phenomenological equations successfully describe irreversible thermodynamic processes. They assume a symmetric coupling matrix between thermodynamic fluxes and forces. It is easily shown that the antisymmetric part of a coupling matrix does not contribute to dissipation. Therefore, entropy production is exclusively governed by the symmetric matrix even in the presence of antisymmetric...